Neoprene is more like leather than Lycra or rubber. It is thicker and structural, where Lycra of rubber stretch and conform to the body's shape Neoprene will impose it's own shape over the body.
If you are certain you want a fem look then go for it.
The alternative is a butch male look as expressed here:
https://www.etsy.com/uk/listing/2881...grid_organic=1
Consider as a synthetic alternative to leather.